The CLIO free electron laser ( Orsay, France)
IRMPD-Infrared spectroscopy integrated into mass spectrometry

The room is equipped with a FT-ICR type hybrid mass spectrometer equipped with a 7 T magnet (Bruker Apex Qe). It is coupled either to the free electron laser or to an OPO / OPA laser (2.5 -5 μm) or to a Co2 laser (10.6 μm). This arrangement makes it possible to derive the IR spectra of the ions within the mass spectrometer.

Ions are put into the gas phase thanks to an ESI or nano ESI source. The introduction line used for CID fragmentation (Collisinal Induced Dissociation), has been modified to introduce neutral molecules directly into the collision cell in order to produce an ion-molecule reaction.
This device is part of the FT-ICR national high-field mass spectrometry network

Additional Lightsources

Laser Co2

Laser type
Co2
Central Wavelength/Energy
10.6 * 103 [nm]
Beam shape
Gaussian
Polarisation
Linear Vertical
Peak power
10 [W]
Pointing stability at the source
200 [urad]

OPO/OPA

Laser type
Amplified OPO
Central Wavelength/Energy
2.5 * 103 [nm]
Spectral Bandwidth FWHM
2500 - 5000 [nm]
Tunability
1 * 102 [%]
Beam shape
Gaussian
Pulse duration FWHM
8 [ns]
Polarisation
Linear Horizontal
Pulse repetition rate
10 [Hz]
Maximum pulse energy
17 [mJ]
Peak power
2.1 * 106 [W]
contacts
Philippe Maitre
Techniques
Absorption
  • IR spectroscopy
Ion Spectroscopy
  • Mass spectrometry
Disciplines
Chemistry
  • Atoms, molecules, clusters and gas-phase chemistry
  • Biochemistry
  • Physical Chemistry
Life Sciences & Biotech
  • Medicine
  • Molecular and cellular biology
  • Protein and macromolecular structures
Physics
  • Astronomy/Astrophysics/Astroparticles
  • Atomic & molecular physics
control/Data analysis