SPECIES is an undulator based soft X-ray beamline, located at the 1.5 GeV storage ring. The offered experimental techniques are Ambient Pressure X-ray Photoelectron Spectroscopy (APXPS), X-ray Absorption Spectroscopy (XAS), X-ray Emission Spectroscopy (XES) and Resonant Inelastic X-ray Scattaring (RIXS). The beamline has two branches that use a common elliptically polarizing undulator (EPU61) and a monochromator (PGM), providing photon energy range of 30 – 1500 eV. The beam is changed between the two branches by changing the refocusing optics after the PGM. Both branches have separate exit slits, refocusing optics and dedicated permanent end stations (APXPS and RIXS).

The APXPS end station is equipped with an electrostatic analyser for XPS and XAS on surfaces under UHV and at near ambient pressure conditions (up to 10-20 mbar). The end station is especially well suited for studies on solid-vapour/gas-liquid interfaces. This is, for example, relevant for studies of corrosion processes, heterogeneous catalysis, and charge/discharge cycling of batteries, film growth etc. We work in close collaboration with the HIPPIE beamline.

The RIXS end station has two spectrometers covering the wide energy range from 30 to 1000 eV. It will support measurements on various kinds of samples ranging from solids to liquids and gas-phase, and problems related to the molecular structure of liquid water, mixtures, and solutions can be addressed. Furthermore, the RIXS spectroscopy can be used to investigate cycling effects on the electronic structure of electrodes in Li-ion battery electrodes as well as of corrosion processes of transition metals. The end station provides also a NEXAFS detector and a manipulator with sample scanning capability.

Our RIXS users benefit also from our close collaboration with the VERITAS beamline, which, for example, simplifies sharing of samples between the beamlines due cross compatible sample manipulation and enables users to carry out the same experiment at the both beamlines.

Endstations or Setup

APXPS endstation

Description
APXPS endstation:
The SPECIES APXPS endstation is designed for ambient-pressure XPS measurements using dedicated cells. The endstation is equipped with UHV manipulator to facilitate normal measurements in UHV conditions with sample heating and some sample preparation methods. Dedicated ambient pressure cells enable measurements to be carried out at higher gas pressures.
Spectrometer
SPECS Phoibos 150 NAP electron spectrometer
Base Pressure
5 * 10-10 [mbar]
Endstation Operative
Yes

Sample

Sample Type
Other: Surfaces and thin films.
Mounting Type
Omicron flag-type sample holder.
Sample size up to approximately 8 mm x 8 mm.

Manipulator or Sample stage

Description
Analysis chamber manipulator:
X, Y, Z, rot (UHV manipulator)
X, Y, Z (AP cells)

Sample Environment

Description
Analysis chamber:
Supports UHV XPS with sample on manipulator. Cooling to -30 C and heating to 600 C is available.

Ambient-pressure XPS is facilitated by the use of special cells. A standard ambient-pressure cell for e.g. catalysis and oxidation studies is in operation, as well as an ALD ambient-pressure cell. The cell window thickness and material: 200 nm Al (default) and 200 nm Si3N4 (upon request).
Gas dosing with 2 gas types is available.

A quadrupole mass spectrometer that can sample inlet and outlet is available (Dycor LCD200 up to 200 amu range).
Pressure (min)
2 * 10-10 [mbar]
Pressure (Max)
20 [mbar]
Temperature
243 - 1273 [K]
Description
Load lock:
30 min transfer time from air.
Pressure (min)
2 * 10-8 [mbar]
Description
Preparation chamber:
- SPECS Ar sputter gun.
- SPECS ErLEED.
- Focus EFM 3T triple cell evaporator.
- Possibility to leak in several gases.
- Electrospray is available upon special request.
Pressure (min)
2 * 10-10 [mbar]
Temperature
295 - 1273 [K]
contacts
Esko Kokkonen
Techniques
Absorption
  • NEXAFS
Photoelectron emission
  • UPS
  • XPS
Scattering
  • Resonant scattering
Disciplines
Chemistry
  • Atoms, molecules, clusters and gas-phase chemistry
Material Sciences
  • Knowledge based multifunctional materials
Physics
  • Hard condensed matter - electronic properties
control/Data analysis
Control Software Type
  • Tango/SPECS
Data Output Type
  • 1D spectra
Data Output Format
  • HDF5 / SPECS