FAME-UHD, the French Absorption spectroscopy beamline in Material and Environmental sciences at Ultra-High Dilution, is dedicated to high energy resolution fluorescence detected x-ray absorption spectroscopy (HERFD-XAS) for structural investigation of ultra-diluted samples. The key element of the beamline is thus a crystal analyser spectrometer, which enables XANES analyses at concentrations as low as 1ppm and EXAFS at 10ppm.

 

This low detection limit is obtained thanks to the combination of state-of-the-art cooled optics (designed firstly to maximize the photon flux on the sample and secondly to optimize the beamline stability and reduce the non-statistical noise) and multi-crystal analyser spectrometer.

 

This is of particular interest for environmental and biological systems: study of trace elements in soils, effect of pollutants at low concentrations...

 

Opened to users since January 2017, the beamline is designed to accept easily different sample environments: the beamline helium cryostat but also, HP-HT vessel, electrochemical cells, cells for gaseous reactions...

 

FAME-UHD is one of the French CRG beamlines at the ESRF: beamtime can be asked both through the ESRF and the Soleil program committees.

Beamline Energy Resolution
6 * 10-1 [eV] @ 12 [eV]
Beamline Energy Range
4800 - 20000 [eV]
Spot Size On Sample Hor
150 - 250 [um]
Spot Size On Sample Vert
80 - 150 [um]
Photon Sources

0.8T ESRF BM

Type
Bending Magnet
Available Polarization
Linear horizontal
Monochromators

FAME-UHD monochromator

Energy Range
4900 - 25000 [eV]
Type
Si[220] 2-crystals, liquid nitrogen cooled, sagittal bending (horizontal focussing).
Pre-focusing Mirror Type
Mirror for vertical collimation and harmonic rejection: Rh-coated, variable incidence angle (2.5 to 7mrad) and variable curvature.
Refocusing Mirror Type
Mirror for vertical focussing and harmonic rejection: Rh-coated, variable incidence angle (2.5 to 7mrad) and variable curvature.
Endstations or Setup

Spectrometer

Spectrometer
Crystal Analyser Spectrometer
Base Pressure
1 * 103 [mbar]
Detectors Available
Transmission mode
Crystal Analyser Spectrometer
Endstation Operative
Yes

Sample

Sample Type
Crystal, Amorphous, Powder, Liquid

Manipulator or Sample stage

Translator Stages
5
Positioning Precision
X = 1 [um], Y = 1 [um], Z = 1 [um]
Range Of Movement
X = 5 [mm], Y = 20 [mm], Z = 40 [mm]

Sample Environment

Description
Operando reactor with remote gas control system
Pressure (min)
1 [bar]
Pressure (Max)
1000 [bar]
Temperature
300 - 1300 [K]
Description
Continuous flow helium cryostat
Temperature
4 - 300 [K]
Description
Large volume high pressure / high temperature vessel
Pressure (min)
1 [bar]
Pressure (Max)
2000 [bar]
Temperature
293 - 1500 [K]
Detectors

Crystal Analyser Spectrometer

Type
Crystal Analyser Spectrometer
Description
14 bent crystals (1m) + Ketek SDD detector located on the Rowland Circle
Passive or Active (Electronics)
Active

Detection

Detected Particle
Photon

Transmission mode

Type
Diodes
Description
Si diodes collecting photons scattered by air in a black chamber for both incident and transmited intensity measurements
Passive or Active (Electronics)
Active

Detection

Detected Particle
Photon
contacts
Jean-Louis HAZEMANN
Denis TESTEMALE
Olivier PROUX
Isabelle KIEFFER
Mauro ROVEZZI
Antonio AGUILAR TAPIA
Techniques
Absorption
  • EXAFS
  • NEXAFS
Emission or Reflection
  • X-ray fluorescence (XRF)
Disciplines
Chemistry
  • Biochemistry
  • Catalysis
  • Electrochemistry
  • Green Chemistry
  • Physical Chemistry
Earth Sciences & Environment
  • Geology
  • Mineralogy
  • Natural disaster, Desertification & Pollution
  • Plant science
  • Water sciences/Hydrology
Energy
  • Sustainable energy systems
Humanities
  • Cultural Heritage
Life Sciences & Biotech
  • Molecular and cellular biology
Material Sciences
  • Other - Material Sciences
Physics
  • Hard condensed matter - structures
control/Data analysis
Control Software Type
  • BLISS
Data Output Type
  • spectra (X: Energy, Y: absorption in fluorescence, transmission, temperature of measurement...)
Data Output Format
  • HDF5
Softwares For Data Analysis
  • Larix (XAS normalization and EXAFS analysis) , FDMNES (XANES analysis)
Equipment That Can Be Brought By The User
Windows and volume should be adapter to the spectrometer. Contact the beamline staff to discuss.